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At The Equilibrium / Projected Futures: Equilibrium : And hence gibbs free energy equals to zero. . B) at t2 the temperature of the reaction vessel is increased and allowed to reach equilibrium once again. So this reason, there is no work done by the system. This page looks at le chatelier's principle and explains how to apply it to reactions in a state of dynamic equilibrium. I am talking about the state of a physical system, that can be found in/at equilibrium. By substituting demand and supply formula to the given example equilibrium quantity and price can be. If a market is at its. Equilibrium shifts to the left. That is, when a new equilibrium is reached there will be less product look at the given equation and decide whether the rate of the forward reaction or the rate of the. A system is at equilibrium when the rates of the forward and reverse reactions are equal. The equilibrium constant is independent of the concentration of the species involved.